Boost Octane and Throughput of C5 Isomerization Units

DWC Innovations / 24 July, 2026 / Whitepapers

This DWC Innovations whitepaper explains how dividing wall column (DWC) technology can boost octane and throughput in light-naphtha isomerization units. Conventional once-through isomerization typically yields a RON near 85, while adding recycle columns like a deisohexanizer, deisopentanizer, or depentanizer raises RON further but usually needs costly new columns. Revamping the existing deisohexanizer into a dividing wall column lets one vessel take on this added duty, lifting RON without new equipment.

Up to 93Isomerate RON achieved
+5-20%Throughput increase
1Revamped DWC vessel
0New columns needed
Revamp scenarios

Results delivered

RON improved from 87–88 to 89–90, with a 10–20% increase in throughput

RON improved from 89–90 to 91–93, with a 5–10% increase in throughput

One revamped column handles hexane recycle plus deisopentanizing or depentanizing duty

Lower capital cost and footprint than installing new columns

The whitepaper

Boost Octane & Throughput with DWC

Read the full paper — revamping a deisohexanizer into a dividing wall column to lift isomerate RON and throughput without installing new columns.

The revamp

Revamping the existing deisohexanizer into a dividing wall column lets one vessel take on hexane recycle plus deisopentanizing or depentanizing duty — lifting isomerate RON (up to 91–93) and throughput by 5–20%, at lower capital cost and footprint than new columns.